Search results for "Isotopes of sodium"

showing 3 items of 3 documents

The effect of salt content on the structure of iota-carrageenan systems: Na-23 DQF NMR and rheological studies

2009

International audience; 23Na NMR spectroscopy has been used to study the effects of Na+ ion concentrations on the structure of 1% (w/w) iota-carrageenan systems, a natural gelling polysaccharide used as a thickener in the food industry. Rheological and 23Na T1 relaxation time measurements revealed that gel formation correlates with decreases in ion mobility over the range of 0-3% (w/w) sodium content. 23Na single-quantum (SQ) and double-quantum-filtered (DQF) NMR experiments performed on these systems provided evidence for a bound sodium ion fraction in a specifically ordered environment. These results have allowed us to propose a model for the carrageenan gelation mechanism in the presence…

Magnetic Resonance SpectroscopySodiumchemistry.chemical_elementSodium Chloride010402 general chemistryPolysaccharideCarrageenan01 natural sciencesDOUBLE-QUANTUM FILTERIonchemistry.chemical_compound0404 agricultural biotechnologyRheologyRHEOLOGY23NA[CHIM.ANAL]Chemical Sciences/Analytical chemistryMoleculeGeneral Materials ScienceIOTA-CARRAGEENANchemistry.chemical_classificationChromatographyMolecular Structure04 agricultural and veterinary sciencesGeneral ChemistryNuclear magnetic resonance spectroscopyIsotopes of sodium040401 food scienceNMR0104 chemical sciencesCarrageenanchemistrySODIUM BINDING STATEQuantum TheorySodium IsotopesNuclear chemistry
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Optical polarization of neutron-rich sodium isotopes and β-NMR measurements of quadrupole moments

1996

The nuclear quadrupole moments of neutron-rich sodium isotopes are being investigated with the help of in-beam polarization by optical pumping in combination with $\beta$-NMR techniques. First measurements have yielded the quadrupole splittings of NMR signals in the lattice of LiNbO$_{3}$ for the isotopes $^{26}$Na, $^{27}$Na and $^{28}$Na. Interaction constants and ratios of the electric quadrupole moments are derived. In view of future experiments, $\beta$-decay asymmetries for the sequence of isotopes up to the $N$=20 neutron shell closure, $^{26-31}$Na, have been measured.

Nuclear and High Energy PhysicsIsotopeChemistryNuclear TheoryAnalytical chemistryOptical polarizationQuadrupole splittingCondensed Matter PhysicsIsotopes of sodiumPolarization (waves)Atomic and Molecular Physics and OpticsOptical pumpingQuadrupolePhysics::Accelerator PhysicsNuclear Physics - ExperimentNeutronPhysics::Atomic PhysicsPhysical and Theoretical ChemistryAtomic physicsNuclear Experiment
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Experimental studies of the NaRb ground-state potential up to thev″=76level

2002

Laser induced fluorescence spectra of the C {sup 1}{sigma}{sup +}-X {sup 1}{sigma}{sup +} system of {sup 23}Na{sup 85}Rb and {sup 23}Na{sup 87}Rb have allowed vibrational levels of the electronic ground state up to v{sup ''}=76, spanning 99.85% of the potential well to be observed. The ground-state term values have been fitted to a Dunham polynomial expansion, and also to a direct modified Lennard-Jones (MLJ) potential. The analytical MLJ construction allowed us to match previous measured term values for v{sup ''}{<=}30 with long-range behavior of the potential through the intermediate internuclear distance region covered by the present investigation.

PhysicsLennard-Jones potentialTheoryofComputation_ANALYSISOFALGORITHMSANDPROBLEMCOMPLEXITYKinetic isotope effectSigmaAtomic physicsGround stateIsotopes of sodiumLaser-induced fluorescencePotential energyAtomic and Molecular Physics and OpticsSpectral linePhysical Review A
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